By means of the stochastic theory of nonequilibrium thermodynamics the thermodynamical and the statistical problems concerned with the absolute rate theory are commented. 作者根据非平衡态热力学的随机理论,对反应速度活化络合物理论涉及的热力学及统计力学问题给予了评论;
The liquid diffusion theories& hydrodynamic theories, absolute rate theory and others; 液相扩散理论,包括流体动力扩散理论。
Combined with the state equation of chain-like fluids, a model for correlating and predicting viscosities of liquid mixtures under high pressures was established based on Eyring's absolute rate theory. 在压力型Eyring理论的基础上,结合链流体状态方程建立了一个高压流体混合物的粘度模型。
In order to understand the anomalous decomposition behavior of propylene carbonate ( PC) on a graphite electrode, the reaction mechanism for the decomposition of propylene and ethylene carbonate ( EC) was studied by means of absolute rate theory with semi empirical molecular orbital calculations. 应用半经验分子轨道计算绝对速率理论,研究了乙烯和丙烯碳酸酯(EC,PC)分解的反应机理,推断了丙烯碳酸酯在石墨阳极上反常分解行为。